Use Array.maxBy method:
val a = Array(("a",1), ("b",2), ("c",1), ("d",3))
val maxKey = a.maxBy(_._2)
// maxKey: (String, Int) = (d,3)
or RDD.max:
val maxKey2 = rdd.max()(new Ordering[Tuple2[String, Int]]() {
override def compare(x: (String, Int), y: (String, Int)): Int =
Ordering[Int].compare(x._2, y._2)
})