K-means initialization in Scikit-learn is set using the init parameter, where "k-means++" optimizes cluster center selection for faster convergence and better performance.
Here is the code snippet you can refer to:

In the above code we are using the following key points:
- Uses make_blobs to generate synthetic clusterable data.
- Applies KMeans with "k-means++" for efficient centroid initialization.
- Visualizes the clustered data and cluster centers.
Hence, using "k-means++" initialization in KMeans ensures faster convergence and more accurate clustering by starting with well-placed initial centroids.