This question asks: Which tools may not align with the DevOps framework, meaning they do not directly support automation, continuous integration/continuous deployment (CI/CD), configuration management, monitoring, or infrastructure provisioning? While it is unlikely that they definitely won't because, in the context of DevOps, tools usually improve the capability of collaboration between development teams and operations and reduce the number of repetitive tasks and speed up the process of application deployment.
While evaluating something for its relevance to DevOps, how it contributes to faster and more reliable software delivery in ways that are collaborative should be the focus.